Material Insights · Understanding the Material World

Acrylonitrile

Acrylonitrile is a propylene-and-ammonia intermediate used to make ABS plastic, acrylic fibre, acrylamide, nylon 66 precursors and carbon fibre.

Commodity chemicals · Derivatives & intermediates · No. 41

  • Single chemical
  • Feedstock: Oil, gas or coal
  • about 7 Mt a year of demand (2025, indicative)
  • 3.4 t CO₂e per t
  • HS 292610
Commodity chemicals · Derivatives & intermediates · Foundation · Matter

The same molecule toughens your phone case, warms your acrylic jumper and goes into lightweight carbon fibre.

Chart: Illustration: Acrylonitrile

Where it comes from

Chart: Map of where it comes from

Propylene, ammonia and air react over a bismuth-molybdate catalyst in a fluidised bed. The reaction gives off so much heat that plants export high-pressure steam.

Three things to know
  1. Almost all acrylonitrile is still made by the SOHIO ammoxidation process first introduced in 1960.
  2. Prices slid from about $1.30 per kg CFR South Asia in January 2025 to about $1.04 in February 2026.
  3. India's only plant, Reliance's 24 kt unit at Vadodara, has made nothing since at least 2016-17, so nearly all supply is imported.
The journey
  1. 1 Propylene, ammonia1.1 t propylene, 0.48 t ammonia
  2. 2 AmmoxidationFluidised bed at 400-500 C
  3. 3 RecoveryDistilled from HCN and acetonitrile
  4. 4 Inhibited liquidShipped under nitrogen to stop polymerising
  5. 5 DerivativesABS, acrylic fibre, acrylamide, nylon 66
Covered in The chemical industry: what it makes and how it is organisedChemicalsFrom building blocks to plastics, fibres and detergentsChemicalsPharmaceuticals and fermentation: from molecule to medicineChemicals
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