Material Insights · Understanding the Material World

Caprolactam: Feedstocks

Benzene, ammonia and sulphur, and the fertiliser credit

What this tab covers What it is made from and what it feeds: the raw materials and energy per tonne with their share of cost (linked to the commodity table), who is low-cost and why, and the chemicals made from it.

Caprolactam combines aromatics (benzene or phenol), nitrogen (ammonia) and sulphur (oleum). Benzene is the main cost. The ammonium sulphate credit matters: when fertiliser prices are high, by-product revenue cushions margins, and when they fall, conventional plants suffer most. Coal-based Chinese groups with captive benzene, hydrogen and ammonia are lowest cost.

Inputs per tonne

InputQuantity per tonneRoleShare of costSource
Oil Crude oilabout 0.9 t benzene per t (indicative)carbon ringabout 55-65% of cash cost (indicative)indicative
Kc Coking coalindirectbenzene source for coke-chemical groups such as China Risunincluded aboveindicative
Gas Natural gasabout 0.15-1 t ammonia per t depending on route (indicative)nitrogen source and hydrogenabout 10-15% (indicative)indicative
S Sulfurabout 0.4-1.2 t sulphuric acid equivalent per t (indicative)Beckmann rearrangementabout 5% (indicative)indicative
Hydrogen peroxideabout 0.3-0.35 t (100%) in ammoximation (indicative)oxidantabout 5-8% (indicative)indicative

Who is low-cost, and why

Chinese ammoximation plants integrated with benzene, hydrogen and ammonia, often coal-based, are lowest cost. Older European, Japanese and Indian plants with Raschig routes are higher cost and depend on ammonium sulphate credits.

Raw materials on the commodity table

Oil Crude oilS Sulfur

What it is made into

ProductNote
PA Nylon (PA6, PA66)essentially all caprolactam
AS Ammonium sulphateco-product, about 1.3-4.4 t per t