Material Insights · Understanding the Material World

Propylene oxide: Emissions

Route and co-product accounting swing the footprint

What this tab covers The greenhouse-gas footprint per tonne, split by lifecycle phase (feedstock, production, movement, use, end of life), the global total, other environmental impacts, levers and low-carbon routes, India's position, and where the investment opportunity lies. Emission intensity 2.50 t CO2e per t range about 1.5-4 depending on route and co-product allocation · cradle-to-gate, mixed routes (indicative) Global emissions per year 30.0 Mt CO2e per year 2025 · about 2.5 t x about 12 Mt (indicative)

Per t of PO, cradle-to-gate. Intensity: indicative (basis: Plastics Europe eco-profiles and route LCAs). Global total: derived (indicative).

Share of footprint by lifecycle phase

Feedstock 48% Production / process 48% Movement 4%

Footprint by lifecycle phase

PhaseIntensityShareMain sources of emissionsNotesSource
Feedstockabout 1.2 t CO2e per t48%Propylene (about 0.8 t at about 1.5 t CO2e/t)indicative
Production / processabout 1.2 t CO2e per t48%Oxidant production (chlor-alkali power, H2O2 from SMR hydrogen), steam for separationsHPPO is lowest; chlorohydrin highestindicative
Movementabout 0.1 t CO2e per t4%ISO tanks and parcel tankersindicative
Usenot applicable–Converted into polyolsPU foam blowing agents are a separate GHG issuen/a
End of lifedepends on PU foam fate–Mattresses and insulation landfilled or incineratedPU recycling is limitedn/a

Other environmental impacts

Chlorohydrin route generates about 40-50 t of salty wastewater per t PO (indicative); PO is a hazardous air pollutant.

Levers to cut emissions

  • Replace chlorohydrin with HPPO (no chlorine, water by-product).
  • Low-carbon hydrogen for hydrogen peroxide.
  • Recycled polyols from PU foam glycolysis or acidolysis.
  • Bio-based propylene glycol from glycerine.

India

India's only PO plant uses the chlorohydrin route (indicative); there is no announced HPPO or bio-PG project in India.

Emission figures are indicative global averages from the life-cycle studies named; actual footprints vary widely by site, energy mix and method.

Low-carbon routes

RouteIntensityCost premiumStatusSource
HPPO replacing chlorohydrinlower than chlorohydrin, and no brine (indicative)none at scaleBASF-Dow Antwerp and Sadara; widespread in Chinaindicative
Bio-propylene glycol from glycerinelower fossil CO2 (not published)depends on glycerine priceADM (US), Oleon (Belgium) (indicative)indicative
Foam-to-polyol recyclingnot publishednot publishedDow RENUVA, Covestro and start-ups at pilot or early commercial scale (indicative)indicative
For a climate investor For India the opportunity is less about cleaner PO and more about import substitution with a modern route: an integrated HPPO-polyol unit near a propylene source would replace imports of polyols and PG. In circularity, mattress and foam recycling to polyols is early but growing, as India's EPR rules extend to more products. Bio-PG from biodiesel glycerine is a niche linked to biodiesel volumes.