Material Insights · Understanding the Material World

Thermochemical storage: What to track

An R&D bet: cycle stability and the first real orders

What this tab covers The attributes worth tracking regularly, with the latest value, the direction of travel and why each matters.

Treat as an R&D bet: track cycle stability, pilot results and whether any firm reaches commercial orders.

CategoryAttributeLatestTrendWhy it matters
Techno-economicLCOS trajectory (capex outlook)No LCOS found; oxide storage estimated USD 15-100 per kWh; IRENA expects as low as USD 10 by 205015↗ improving Long-dated target with high uncertainty.
TechnicalCapacity fade and state of health (cycle stability)CaO residual conversion 7.5% (model assumption); Ti-doped Mn2O3 loses 53-63% of uptake in 30 cycles46↗ improving Sintering is the main barrier; dopants and stabilisers are the fix being tested.
Supply chainCritical mineral cost and geopolitical concentrationMostly abundant materials; cobalt oxide is the exception5→ stable Choice of oxide sets mineral exposure.
MarketAncillary service market saturationNot relevant; slow response suits seasonal heat1→ stable Value lies in long-duration heat.
RegulatorySafety and environmental complianceProcess and pressure rules; some salts release HCl3→ stable No dedicated standards yet.
ImpactLifecycle carbon payback periodEnergy payback 2.2-2.5 years for a calcium looping solar plant9→ stable Shows the embodied footprint is small.
TechnicalPilot scale reachedCREATE 182 kWh (Warsaw); SaltX 0.5 MW / 10 MWh (Berlin)27↗ improving First proof points outside the laboratory.
TechnicalTechnology readinessMostly prototype (IRENA 2020); salt hydration expected to advance in 5-10 years1↗ improving Indicates investment horizon.

Sources

  1. Innovation Outlook: Thermal Energy Storage IRENA, 2020
  2. Review of Carnot Battery Technology Commercial Development (Novotny et al., Energies 15(2), 647) MDPI, 2022
  3. A review of salt hydrates for seasonal heat storage in domestic applications (Donkers et al., Applied Energy 199, 45-68) Eindhoven University of Technology repository, 2017
  4. Operation maps in calcium looping thermochemical energy storage for concentrating solar power plants (Pascual, Lisbona and Romeo, Journal of Energy Storage 55, 105771) University of Zaragoza repository, 2022
  5. Lessons Learned: Developing Thermochemical Cycles for Solar Heat Storage Applications (Wong, General Atomics; conference slides, DOE Workshop on TES for CSP, January 2013) US Department of Energy, 2013
  6. Effects of TiO2 doping on the performance of thermochemical energy storage based on Mn2O3/Mn3O4 redox materials (Wang, Wang, Dou, Ma and Liang, RSC Advances 2021) Royal Society of Chemistry, 2021
  7. Compact thermochemical heat storage prototype (CREATE project, IEA SHC Task 58) IEA Solar Heating and Cooling Programme, 2020
  8. Life cycle and environmental assessment of calcium looping (CaL) in solar thermochemical energy storage (Colelli et al., Energy Conversion and Management 257, 115428) Elsevier, 2022