Thermochemical storage: What to track
An R&D bet: cycle stability and the first real orders
What this tab covers The attributes worth tracking regularly, with the latest value, the direction of travel and why each matters.Treat as an R&D bet: track cycle stability, pilot results and whether any firm reaches commercial orders.
| Category | Attribute | Latest | Trend | Why it matters |
|---|---|---|---|---|
| Techno-economic | LCOS trajectory (capex outlook) | No LCOS found; oxide storage estimated USD 15-100 per kWh; IRENA expects as low as USD 10 by 205015 | ↗ improving | Long-dated target with high uncertainty. |
| Technical | Capacity fade and state of health (cycle stability) | CaO residual conversion 7.5% (model assumption); Ti-doped Mn2O3 loses 53-63% of uptake in 30 cycles46 | ↗ improving | Sintering is the main barrier; dopants and stabilisers are the fix being tested. |
| Supply chain | Critical mineral cost and geopolitical concentration | Mostly abundant materials; cobalt oxide is the exception5 | → stable | Choice of oxide sets mineral exposure. |
| Market | Ancillary service market saturation | Not relevant; slow response suits seasonal heat1 | → stable | Value lies in long-duration heat. |
| Regulatory | Safety and environmental compliance | Process and pressure rules; some salts release HCl3 | → stable | No dedicated standards yet. |
| Impact | Lifecycle carbon payback period | Energy payback 2.2-2.5 years for a calcium looping solar plant9 | → stable | Shows the embodied footprint is small. |
| Technical | Pilot scale reached | CREATE 182 kWh (Warsaw); SaltX 0.5 MW / 10 MWh (Berlin)27 | ↗ improving | First proof points outside the laboratory. |
| Technical | Technology readiness | Mostly prototype (IRENA 2020); salt hydration expected to advance in 5-10 years1 | ↗ improving | Indicates investment horizon. |
Sources
- Innovation Outlook: Thermal Energy Storage IRENA, 2020
- Review of Carnot Battery Technology Commercial Development (Novotny et al., Energies 15(2), 647) MDPI, 2022
- A review of salt hydrates for seasonal heat storage in domestic applications (Donkers et al., Applied Energy 199, 45-68) Eindhoven University of Technology repository, 2017
- Operation maps in calcium looping thermochemical energy storage for concentrating solar power plants (Pascual, Lisbona and Romeo, Journal of Energy Storage 55, 105771) University of Zaragoza repository, 2022
- Lessons Learned: Developing Thermochemical Cycles for Solar Heat Storage Applications (Wong, General Atomics; conference slides, DOE Workshop on TES for CSP, January 2013) US Department of Energy, 2013
- Effects of TiO2 doping on the performance of thermochemical energy storage based on Mn2O3/Mn3O4 redox materials (Wang, Wang, Dou, Ma and Liang, RSC Advances 2021) Royal Society of Chemistry, 2021
- Compact thermochemical heat storage prototype (CREATE project, IEA SHC Task 58) IEA Solar Heating and Cooling Programme, 2020
- Life cycle and environmental assessment of calcium looping (CaL) in solar thermochemical energy storage (Colelli et al., Energy Conversion and Management 257, 115428) Elsevier, 2022