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Acetic acid: Characteristics

Why iodide traces worry vinyl acetate makers

What this tab covers The physical and chemical properties that set its grade, price and uses, with the commercial grades and the standards that define them.

Acetic acid is sold as glacial (water-free) acid to tight purity limits, because VAM and PTA catalysts are sensitive to impurities. Buyers check purity, water, colour, permanganate time and iodide traces left by carbonylation. Freezing at 16.6 C matters for storage and transport.

Properties that matter commercially

PropertyValue / specificationWhy it mattersSource
Purityat least 99.8-99.85% glacial (indicative)downstream catalysts and pharmaindustry specs (indicative)
Waterat most about 0.1-0.15% (indicative)anhydride and VAM processesindicative
Iodidelow ppb levels for VAM grade (indicative)poisons palladium VAM catalystindicative
Freezing point16.6 Cheated storage and tankersphysical data
Flash pointabout 39 Cflammable classificationphysical data

Commercial grades

  • Glacial technical grade
  • VAM grade (low iodide)
  • Food grade (E260)
  • Pharma (IP/USP) grade
  • Diluted acid solutions