Material Insights · Understanding the Material World

Acrylic acid

A propylene-derived acid that makes acrylate esters for paints and adhesives, and superabsorbent polymers for diapers.

Commodity chemicals · Derivatives & intermediates · No. 44

  • Single chemical
  • Feedstock: Oil, gas or coal
  • about 7 Mt a year (2025, indicative)
  • 1.5 t CO₂e per t
  • HS 291611
Commodity chemicals · Derivatives & intermediates · Foundation · Matter

The same propylene acid that binds your wall paint also soaks up the liquid in every disposable nappy.

Chart: Illustration: Acrylic acid

Where it comes from

Chart: Map of where it comes from

Propylene and air pass through two reactors in a row: the first makes acrolein, the second acrylic acid. Over 99% of world capacity uses this route.

Three things to know
  1. About half of acrylic acid becomes esters for water-based paints and adhesives; about a third becomes nappy superabsorbent.
  2. World sales were about $12.0 billion in 2024, forecast to reach about $18.2 billion by 2034.
  3. It freezes at 13 C but can polymerise violently if overheated, so it ships in temperature-controlled tanks at 15-25 C.
The journey
  1. 1 PropyleneAbout 0.7 t per tonne acid
  2. 2 AcroleinFirst oxidation stage at about 330 C
  3. 3 Acrylic acidSecond stage over molybdenum-vanadium, 260 C
  4. 4 Esters or SAPButyl acrylate, or neutralised and cross-linked
  5. 5 End productsPaints, adhesives, nappies, detergents
Covered in From building blocks to plastics, fibres and detergentsChemicalsBiorefineries and platform chemicalsChemicalsBioplastics: PLA, PHA, bio-PE and starch blendsChemicals
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