Material Insights · Understanding the Material World

Bio-based polyethylene and MEG

Polyethylene and MEG made from sugarcane ethanol instead of oil or gas; chemically identical, about 0.2% of PE, sold at a premium.

Bio-based chemicals · Bio-based polymers & platforms · No. 114

  • Single chemical
  • Feedstock: Crops and biomass
  • bio-ethylene capacity 260 kt/yr at Braskem Triunfo (2023); green PE sales 191 kt in 2024, up 23% (S&P Global, Feb 2025); over 1.2 Mt produced 2010-2023
  • -3.0 t CO₂e per t
  • HS 390110
Bio-based chemicals · Bio-based polymers & platforms · Foundation · Matter

Some shampoo bottles are made of plastic grown in Brazilian cane fields, chemically identical to plastic from oil.

Chart: Illustration: Bio-based polyethylene and MEG

Where it comes from

Chart: Map of where it comes from

Cane ethanol is passed over a hot catalyst to make ethylene, then polymerised in ordinary reactors; it takes about 1.7-1.75 t of ethanol per tonne of ethylene.

Three things to know
  1. Braskem's 2023 expansion cost $87 million and raised Triunfo's capacity by 30% to 260 kt a year.
  2. Braskem's 2025 study puts bio-HDPE about 5 kg CO2e per kg better than fossil HDPE.
  3. Over 1.2 Mt of bio-PE was made between 2010 and 2023, almost all at one Brazilian plant.
The journey
  1. 1 SugarcaneAbout 80-85 litres of ethanol per tonne
  2. 2 EthanolTrucked from mills to Triunfo, southern Brazil
  3. 3 DehydrationCatalyst at 350-450 C makes ethylene
  4. 4 PolymerisationStandard reactors make HDPE, LLDPE or EVA
  5. 5 Use and recyclingRecycled with fossil PE, not biodegradable
Covered in The chemical industry: what it makes and how it is organisedChemicals
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