Material Insights · Understanding the Material World

Purified terephthalic acid

The white powder that, with MEG, makes all polyester fibre and PET bottles; China dominates and India is a large importer.

Commodity chemicals · Derivatives & intermediates · No. 40

  • Single chemical
  • Feedstock: Oil, gas or coal
  • about 85 Mt a year of demand (2025, indicative, basis: world PX demand of about 57 Mt at 0.66 t PX per t PTA; China capacity 87-88 Mt run at about 70-75%)
  • 1.3 t CO₂e per t
  • HS 291736
Commodity chemicals · Derivatives & intermediates · Foundation · Matter

A plain white powder, made almost entirely in China, is the backbone of every polyester garment and PET bottle.

Chart: Illustration: Purified terephthalic acid

Where it comes from

Chart: Map of where it comes from

Paraxylene is oxidised with air in acetic acid over a cobalt-manganese-bromide catalyst, then the crude acid is hydrogenated to strip out impurities that would colour the polymer.

Three things to know
  1. Each tonne of polyester needs about 0.86 t of PTA, and 68% of PTA goes into polyester fibre.
  2. Chinese processing fees were around CNY 200 a tonne in July to October 2025, which meant losses for many plants.
  3. India's imports rose 9.1% to 1.95 Mt in January to November 2025 after a quality-control order blocking Chinese supply was revoked.
The journey
  1. 1 ParaxyleneAbout 0.66 t PX per tonne
  2. 2 OxidationAir, acetic acid, cobalt catalyst, 200 C
  3. 3 PurificationHydrogenated over palladium to remove 4-CBA
  4. 4 PolymerisationJoined with MEG into PET melt
  5. 5 End productsYarn, staple fibre, bottle resin, film
Covered in How a chemical process works: reactions, separations, catalysts and flowsheetsChemicalsFrom building blocks to plastics, fibres and detergentsChemicals
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