Material Insights · Understanding the Material World

PHA bioplastics

Polyesters grown inside bacteria from sugar or plant oil that biodegrade in soil and sea; technically promising, commercially fragile.

Bio-based chemicals · Bio-based polymers & platforms · No. 115

  • Product family
  • Feedstock: Crops and biomass
  • not published; tens of kt a year of nameplate capacity (indicative), within 2.31 Mt of bioplastics capacity (2025)
  • HS 391390
Bio-based chemicals · Bio-based polymers & platforms · Foundation · Matter

Bacteria can be starved until they swell with plastic, a plastic that later rots away in seawater.

Chart: Illustration: PHA bioplastics

Where it comes from

Chart: Map of where it comes from

Bacteria fed sugar or plant oil are starved of a nutrient so they store PHA, often 60-80% of their weight, which is then extracted and purified.

Three things to know
  1. Unlike PLA, PHA breaks down in soil, home compost and seawater, not only in industrial composters.
  2. Yield10 Bioscience went bankrupt in December 2024, three months before Danimer filed in March 2025.
  3. Each tonne of PHA needs about 2-3 t of sugar or 1-1.5 t of vegetable oil.
The journey
  1. 1 FeedstockSugar, plant oils, waste oils or methane
  2. 2 FermentationStarved bacteria fill up with PHA
  3. 3 RecoveryCells broken, PHA extracted with solvents
  4. 4 CompoundingBlended with additives, PLA or PBAT
  5. 5 End of lifeBiodegrades in soil, compost and seawater
Covered in The chemical industry: what it makes and how it is organisedChemicals
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