Material Insights · Understanding the Material World

Phosphoric acid

Phosphate rock dissolved in sulphuric acid: the intermediate behind DAP, MAP and most phosphate fertiliser, and now a feed for LFP batteries.

Commodity chemicals · Acids & alkalis · No. 4

  • Single chemical
  • Feedstock: Minerals and salts
  • about 45 Mt P2O5 a year (2025, indicative; most of the 47.8 Mt of P2O5 used in fertiliser passes through wet-process acid, except single superphosphate and direct rock use)
  • 0.5 t CO₂e per t
  • HS 280920
Commodity chemicals · Acids & alkalis · Foundation · Matter

Every tonne of phosphate turned into fertiliser acid leaves up to five tonnes of radium-laced gypsum behind.

Chart: Illustration: Phosphoric acid

Where it comes from

Chart: Map of where it comes from

Phosphate rock is dissolved in sulphuric acid, gypsum is filtered off and the acid is boiled down to 52-54% P2O5; about 45 Mt of P2O5 passes through each year.

Three things to know
  1. Each tonne of P2O5 takes about 3.3 t of rock and 0.9 t of sulphur, so the 2026 sulphur shock flowed straight into acid costs.
  2. India's quarterly acid contract jumped 25% in one quarter, from $1,360 to $1,700 per tonne of P2O5 in Q3 2026.
  3. Morocco holds 68% of the world's phosphate reserves, and its OCP dominates the merchant acid trade.
The journey
  1. 1 Rock miningAbout 250 Mt of phosphate rock
  2. 2 Sulphur burningSulphuric acid made on site
  3. 3 DigestionRock dissolved, gypsum filtered off
  4. 4 ConcentrationEvaporated to 52-54% P2O5
  5. 5 GranulationAmmoniated into DAP and MAP
  6. 6 Gypsum stacks4.5-5 t waste per tonne P2O5
Covered in The chemical industry: what it makes and how it is organisedChemicalsHeavy inorganics: salt, sulphur, nitrogen and phosphorusChemicalsFrom building blocks to plastics, fibres and detergentsChemicalsScale, capacity and feedstock: which chemical plants get builtChemicals
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