Material Insights · Understanding the Material World

Plasticisers

Oily esters that make PVC soft and flexible for cables, flooring, film and medical tubing; a 9-10 Mt market moving away from older phthalates.

Specialty chemicals · Performance additives · No. 77

  • Product family
  • Feedstock: Oil, gas or coal
  • about 9-10 Mt a year (2024, indicative: widely cited industry estimates; no public total retrieved)
  • 2.5 t CO₂e per t
  • HS 291732
Specialty chemicals · Performance additives · Foundation · Matter

The softness of a cable sheath or vinyl floor comes from oily esters that can make up half the plastic.

Chart: Illustration: Plasticisers

Where it comes from

Chart: Map of where it comes from

An acid such as phthalic anhydride from o-xylene is reacted with an alcohol; one tonne of DOP needs about 0.38 t of anhydride and 0.67 t of 2-EH.

Three things to know
  1. A plasticiser is about two-thirds alcohol by weight, so 2-ethylhexanol makes up about 55-65% of the cost.
  2. EU rules have limited four low phthalates such as DEHP to 0.1% in articles, pushing makers towards DOTP and DINCH.
  3. In August 2026 India put anti-dumping duties of $40.08/t on Chinese and $140.17/t on Korean phthalic anhydride.
The journey
  1. 1 Aromatics, olefinsXylenes and propylene from oil refining
  2. 2 Acid and alcoholPhthalic anhydride or PTA, plus 2-ethylhexanol
  3. 3 EsterificationReacted at about 200-230 C with catalyst
  4. 4 Clear liquidStripped, filtered, shipped in tanks
  5. 5 Flexible PVCCables, flooring, film and medical tubing
Covered in Bioplastics: PLA, PHA, bio-PE and starch blendsChemicals
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