Material Insights · Understanding the Material World

Surfactants

Surfactants are the cleaning molecules in detergents, shampoos and industrial processes; a $49 billion, roughly 18 Mt market split between oil-based and palm- or coconut-based chains.

Specialty chemicals · Industrial & consumer specialties · No. 86

  • Product family
  • Feedstock: Oil, gas or coal
  • about 17-20 Mt a year excluding soap (indicative, basis: about 5.8 Mt LAS from 4.4 Mt LAB, about 6-7 Mt of ethoxylates from about 4 Mt EO, plus alcohol sulphates, cationics and amphoterics)
  • 2.5 t CO₂e per t
  • HS 340211, 340213
Specialty chemicals · Industrial & consumer specialties · Foundation · Matter

Every detergent, shampoo and toothpaste relies on a molecule with a water-loving head and a grease-loving tail.

Chart: Illustration: Surfactants

Where it comes from

Chart: Map of where it comes from

The oily tail comes from kerosene and benzene or from palm kernel and coconut oil; a tonne of LAS acid needs about 0.74 t of LAB.

Three things to know
  1. LAS, made from linear alkylbenzene, is roughly 30% of surfactant volume because it is the cheapest strong cleaner.
  2. Petro-based fatty alcohol averages about 2.97 kg CO2e per kg, against about 5.27 kg for palm-kernel based.
  3. India is a net exporter of LAS but imported 44% of its LAB raw material in 2020.
The journey
  1. 1 Oil or palmKerosene and benzene, or palm kernel oil
  2. 2 HydrophobeLAB or fatty alcohol makes the oily tail
  3. 3 Head groupSulphonated, sulphated or ethoxylated
  4. 4 Neutralised paste28-70% active pastes and liquids
  5. 5 Cleaning productsDetergents, shampoos, industrial cleaners
Covered in The chemical industry: what it makes and how it is organisedChemicalsFrom building blocks to plastics, fibres and detergentsChemicalsSoaps, detergents and agrochemicalsChemicalsBiorefineries and platform chemicalsChemicals
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